By Prof. Dr. Piet W. N. M. van Leeuwen, Dr. John C. Chadwick(auth.)
This primary publication to light up this significant element of chemical synthesis improves the life of catalysts, hence lowering fabric and saving strength, expenses and waste.
The overseas panel of professional authors describes the stories which were performed about the method homogeneous catalysts decompose, and the variations among homogeneous and heterogeneous catalysts.
the result's a prepared reference for natural, catalytic, polymer and complicated chemists, in addition to these operating in and with/on organometallics.Content:
Chapter 1 common Steps (pages 1–49):
Chapter 2 Early Transition steel Catalysts for Olefin Polymerization (pages 51–89):
Chapter three past due Transition steel Catalysts for Olefin Polymerization (pages 91–103):
Chapter four results of Immobilization of Catalysts for Olefin Polymerization (pages 105–130):
Chapter five Dormant Species in Transition Metal?Catalyzed Olefin Polymerization (pages 131–150):
Chapter 6 Transition steel Catalyzed Olefin Oligomerization (pages 151–175):
Chapter 7 uneven Hydrogenation (pages 177–211):
Chapter eight Carbonylation Reactions (pages 213–278):
Chapter nine Metal?Catalyzed Cross?Coupling Reactions (pages 279–346):
Chapter 10 Alkene Metathesis (pages 347–396):
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Additional info for Homogeneous Catalysts: Activity - Stability - Deactivation
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22 Dppm decomposition via nucleophilic attack. 23 Dppm decomposition via nucleophilic attack. 24 undergoes a PÀC cleavage reaction with methanol giving a phosphinite complex, while the methyl group formed by protonation of the methylene anion shows an agostic interaction with iron . Surprisingly, when 10 bar of CO is applied, the reaction is reversed and the intact NP4 ligand is regenerated. 24 NP4 decomposition via nucleophilic attack. Ruthenium aryloxide complexes containing trimethylphosphine also showed an intramolecular nucleophilic attack, leading to methyl–phosphorus bond breaking and formation of a phosphinite ligand [91a].