By Burke W.L.

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161–162. Translated and quoted in Ramberg, Chemical Structure, p. 57. Carbon double bonds could be envisioned as two tetrahedral sharing an edge, resulting in isomers with the same structure. , p. 59. ), Classics, pp. 156–158. ), Classics, p. 162. ’’ Ramberg, Chemical Structure, p. 60. Le Bel saw two exceptions: (1) When plane of symmetry of the molecule contains the four atoms, A; (2) When the fourth radical is composed of all of the atoms of the first three radicals. ), Classics, p. , p. 163.

Calculations done on amino acids, indicate that the ground-state energies of L-amino acids are lower than those of D-amino acids. Since then, many more accurate calculations have been performed by Schewerdtfeger’s group [25–30] and some recent theoretical calculations found that the effect in excited states could be larger by a factor of 103 [31,32]. This raises the hope that we might be able to measure electroweak energy differences in enantomers in the laboratory. 4 Biomolecular asymmetry Louis Pasteur’s discovery in 1857 that microbes metabolized only the dextro-rotatory sodium-ammonium-tartrate is a momentous one.

A graduate of the E´cole polytechnique, Le Bel then studied at the Colle`ge de France and the E´cole de Me´dicine, where he worked with Wurtz at the same time as Van’t Hoff. It is most likely that Wurtz’s influence was strong in directing Le Bel towards issues of atomic structure, as it was in Van’t Hoff’s case. Le Bel never held an academic post and, unlike Van’t Hoff, who went on to a very distinguished career in chemistry (both as a developer of stereochemistry and as a founder of physical chemistry), Le Bel never followed up his original 1874 article on stereochemistry.

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