By Isaak Babel, Traudel Schaub, Heddy Pross-Weerth (auth.)
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24, unstressed elastomers are disordered and non-crystalline. Interestingly, stressing to produce a high elastic strain, say 200% or more, will induce a significant amount of crystallinity. Stress aligns the chains and produces regions in which repeat units form ordered patterns. 3 Thermosets In the third and remaining category of polymers, known generally as thermosets or network H I -72°C -120°C polymers, the degree of crosslinking is highly developed. As a result, these structures contain many branching points.
Production of filaments, tubes, sheets, shapes and containers). Glasses do not cleave, because there are no crystallographic planes, and fracture to produce new surfaces that are smooth and shell-like (conchoidal). It is usually impossible to represent a glass by a stoichiometric formula. Being essentially metastable, the structure of a glass can change with the passage of time. Raising the temperature increases ionic mobility and hastens this process, being sometimes capable of inducing the nucleation and growth of crystalline regions within the glassy matrix.
8 Silicates Silicate minerals are the predominant minerals in the earth's crust, silicon and oxygen being the most abundant chemical elements. They exhibit a remarkable diversity of properties. Early attempts to classify them in terms of bulk chemical analysis and concepts of acidity/basicity failed to provide an Atomic arrangements in materials effective and convincing frame of reference. An emphasis upon stoichiometry led to the practice of representing silicates by formulae stating the thermodynamic components.